Novel NHC-iridium complexes for advanced application of hyperpolarized NMR

By (author) Simon Osswald

Book cover: Novel NHC-iridium complexes for advanced application of hyperpolarized NMR

Extent: 421, 421 pages

Publisher: Logos Verlag Berlin

Subjects: Earth & Life Sciences 

Series: Beiträge zur organischen Synthese

Series volume number: 103

Language: English

Paperback (Published)

(October 2023)

ISBN: 9783832557218

5.71 x 8.27 inches

Price: $90.00

In stock

Add to cart

Hyperpolarization with parahydrogen emerged as an important method for increasing the signal strength of magnetic resonance measurements like NMR or MRI. In SABRE (signal amplification by reversible exchange) spin order is transferred via a reversibly formed NHC-iridium complex. Recent strategies to apply SABRE in living cells or in vivo in medicine use the separation of the complexes by filtration or heterogeneous catalysts. The development of new heterogeneous systems, biphasic systems and the synthesis of catalysts with improved water solubility are important for the advanced applications of SABRE. In this work, a new class of NHC-iridium-functionalized linker molecules was used to develop metal-organic frameworks for the heterogeneous catalysis in SABRE NMR. The new NHC-iridium complexes were successfully established in SABRE experiments. Additionally, NHC-iridium complexes were modified to be used in a biphasic system of water and fluorinated solvents for an easy separation of the catalyst and the enhanced substrate. Furthermore, novel PEG-functionalized catalysts were designed with improved solubility in water. Efforts made in this work should help to bring forward a promising technology to gain new possibilities in natural science and medicine.

  • By (author) Simon Osswald

Other Titles in this Series

Book cover: Synthesis of Azide-containing Molecules and C3-symmetric Building Blocks Synthesis of Azide-containing Molecules and C3-symmetric Building Blocks

Volume 104

By (author) Lisa Schmidt

Book cover: Development of Rigid Aromatic Building Blocks for the Application in Material Sciences Development of Rigid Aromatic Building Blocks for the Application in Material Sciences

Volume 95

By (author) Yannick Matt

Book cover: Heterobimetallic [2.2]Paracyclophane Complexes and Their Application in Photoredox Catalysis Heterobimetallic [2.2]Paracyclophane Complexes and Their Application in Photoredox Catalysis

Volume 85

By (author) Daniel Knoll

Book cover: Synthesis of Functional Quinoxaline Derivatives for the Application in Biology and Materials Sciences Synthesis of Functional Quinoxaline Derivatives for the Application in Biology and Materials Sciences

Volume 105

By (author) Laura Holzhauer

Book cover: Synthesis and Application of [2.2]Paracyclophane Derivatives in Catalysis and Material Science Synthesis and Application of [2.2]Paracyclophane Derivatives in Catalysis and Material Science

Volume 96

By (author) Christoph Zippel

Book cover: Synthesis and modification of bicyclo[1.1.1]pentyl sulfides Synthesis and modification of bicyclo[1.1.1]pentyl sulfides

Volume 89

By (author) Robin Bar

Book cover: Development of Novel Routes and Methods for the Semisynthesis of the Marine Steroid Demethylgorgosterol and Unnatural Analogs Development of Novel Routes and Methods for the Semisynthesis of the Marine Steroid Demethylgorgosterol and Unnatural Analogs

Volume 97

By (author) Nicolai Rosenbaum

Book cover: Synthesis of Cannabinoid Ligands Synthesis of Cannabinoid Ligands

Novel Compound Classes, Routes and Perspectives

Volume 73

By (author) Thomas Hurrle

Book cover: Synthetic cannabinoids in drug discovery Synthetic cannabinoids in drug discovery

Design, synthesis and evaluation of modified coumarins as CB receptor ligands

Volume 88

By (author) Florian Mohr

Book cover: Design and Synthesis of Emissive and Switchable Photo-Active Molecules Design and Synthesis of Emissive and Switchable Photo-Active Molecules

Volume 98

By (author) Gloria Hong

Book cover: Novel Lanthanide-Based Luminescent Probes for Biological and Lighting Applications Novel Lanthanide-Based Luminescent Probes for Biological and Lighting Applications

Volume 76

By (author) Alena Kalyakina

Book cover: Synthesen trans-A2B2-substituierter Porphyrinlinker zur Darstellung photoaktiver oberflachenverankerter MOF-Dunnschichten Synthesen trans-A2B2-substituierter Porphyrinlinker zur Darstellung photoaktiver oberflachenverankerter MOF-Dunnschichten

Volume 90

By (author) Stefan Marschner

Book cover: Synthesis and design of unsymmetrical quinoxaline-based oligomer with tunable backbone Synthesis and design of unsymmetrical quinoxaline-based oligomer with tunable backbone

Volume 99

By (author) Jerome Klein

Book cover: Structure Performance Relationships of the Novel MALDI-MS Matrices Structure Performance Relationships of the Novel MALDI-MS Matrices

Volume 72

By (author) Suparna Tambe

Book cover: Sulfonyl Ynamides as Useful Tools for N-Heterocyclic Chemistry Sulfonyl Ynamides as Useful Tools for N-Heterocyclic Chemistry

Volume 62

By (author) Tim Wezeman

Book cover: Novel Organic Emitters for Thermally Activated Delayed Fluorescence Novel Organic Emitters for Thermally Activated Delayed Fluorescence

Volume 100

By (author) Celine Leonhardt

Book cover: Metal-Catalyzed N-H and O-H Insertion from alpha-Diazocarbonyl Compounds Metal-Catalyzed N-H and O-H Insertion from alpha-Diazocarbonyl Compounds

Volume 79

By (author) Yuling Hu

Book cover: New Emitters for OLEDs New Emitters for OLEDs

The Coordination- and Photo-Chemistry of Mononuclear Neutral Copper(I) Complexes

Volume 57

By (author) Larissa Bergmann

Book cover: MOF Linkers Based on Porphyrin and Phthalocyanine Structures MOF Linkers Based on Porphyrin and Phthalocyanine Structures

Volume 101

By (author) Lukas Langer

Book cover: Zyklische Hybride – Rigide Modellstrukturen fur neue Theranostika Zyklische Hybride – Rigide Modellstrukturen fur neue Theranostika

Volume 94

By (author) Claudine Herlan

Book cover: Synthesis and Characterization of Luminescent Cu(I) Complexes Synthesis and Characterization of Luminescent Cu(I) Complexes

Volume 58

By (author) Manuela Wallesch

Book cover: Organic Semiconductors based on [2.2]Paracyclophanes and Porphyrins as Hole Transport Materials in Perovskite Solar Cells Organic Semiconductors based on [2.2]Paracyclophanes and Porphyrins as Hole Transport Materials in Perovskite Solar Cells

Volume 102

By (author) Steffen Andreas Otterbach

Book cover: Methods for adapting virtual environments to the challenges of efficient digitization strategies in synthetic chemistry Methods for adapting virtual environments to the challenges of efficient digitization strategies in synthetic chemistry

Volume 83

By (author) Yu-Chieh Huang

Book cover: Synthesis and Biomedical Applications of Multifunctional Poly(ethylene glycol) Derivatives Synthesis and Biomedical Applications of Multifunctional Poly(ethylene glycol) Derivatives

Volume 38

By (author) Ekaterina Sokolovskaya

Book cover: Development of New Synthetic Approaches towards the Anthraquinone-Xanthone Heterodimeric Structure of Beticolin 0 Development of New Synthetic Approaches towards the Anthraquinone-Xanthone Heterodimeric Structure of Beticolin 0

Volume 91

By (author) Janina Beck

Book cover: Computer-Aided Information Retrieval and Management System from Scientific Documents Computer-Aided Information Retrieval and Management System from Scientific Documents

Volume 86

By (author) Thanh Cam An Nguyen

Book cover: Design, Synthesis and Evaluation of Highly Functionalized Peptoids as Antitumor Peptidomimetics Design, Synthesis and Evaluation of Highly Functionalized Peptoids as Antitumor Peptidomimetics

Volume 47

By (author) Carmen Cardenal

Book cover: Design and Synthesis of N-Heterocyclic Donor Based TADF Emitters for Application in OLEDs Design and Synthesis of N-Heterocyclic Donor Based TADF Emitters for Application in OLEDs

Volume 92

By (author) Zhen Zhang

Book cover: Modular Design Strategies for TADF Emitters Modular Design Strategies for TADF Emitters

Towards Highly Efficient Materials for OLED Application

Volume 84

By (author) Fabian Hundemer

Book cover: Virantmycin und Spiculoinsaure A – die intramolekulare Diels-Alder-Reaktionin in der Synthese komplexer Naturstoffe Virantmycin und Spiculoinsaure A – die intramolekulare Diels-Alder-Reaktionin in der Synthese komplexer Naturstoffe

Volume 4

By (author) Daniel Keck

Similar Books

Book cover: Alfonsine Astronomy Alfonsine Astronomy

Computational Practices

Volume 3

Edited by Mathieu Husson Edited by Jose Chabas Edited by Richard Kremer Edited by Matthieu…

Book cover: Ecological Conversion and the Murray River Ecological Conversion and the Murray River

Towards a Changed Relation with a Great River System

By (author) Emmanuel D. Bautista

Book cover: Gravity Gravity

Life's Ups and Downs

By (author) David Howe

Book cover: Naming Pathology from Antiquity to the Early Modern Period Naming Pathology from Antiquity to the Early Modern Period

Volume 20

edited by Alessandra Foscati and Michele Goyens

Book cover: The Tabule Resolute The Tabule Resolute

The Central European Type of Alfonsine Tables

Volume 4

By (author) Petr Hadrava By (author) Alena Hadravová

Book cover: Zoo Quest for a Dragon Zoo Quest for a Dragon

By (author) David Attenborough

Book cover: Zoo Quest to Guyana Zoo Quest to Guyana

By (author) David Attenborough

Book cover: Jan Schröder: Recht als Wissenschaft Jan Schröder: Recht als Wissenschaft

Ein Kommentar

Edited by Marietta Auer Edited by Ralf Seinecke Edited by Stefan Vogenauer

Book cover: „Our house is on fire“ „Our house is on fire“

Theater / Drama / Theatertext und Klimakrise

Volume 5

Volume editor Andreas Englhart Volume editor Artur Pelka Volume editor Hannah von Sass

Book cover: A Mosaic of Recollections A Mosaic of Recollections

Memoirs of an Archaeologist

By (author) David S. Neal

Book cover: Architecture Is Construction Architecture Is Construction

Global Award for Sustainable Architecture

By (author) Marie-Hélène Contal By (author) Jana Revedin By (author) Marta Maccaglia

Book cover: Disaster Resilience and Normalization Disaster Resilience and Normalization

Facing Facts

By (author) Naomi Zack

Book cover: Gardens, Flowers, and Fruit Gardens, Flowers, and Fruit

Proceedings of the Oxford Symposium on Food and Cookery 2024

edited by Mark McWilliams

Book cover: Giovanni Pontano, Commentationes in centum sententiis Ptolemaei Giovanni Pontano, Commentationes in centum sententiis Ptolemaei

A Critical Edition

Volume 5

Edited by Michele Rinaldi

Book cover: Literature and Botany Literature and Botany

Contributions by Piotr Kociumbas Contributions by Marta Czapińska-Bambara Contributions by Siegrun Bubser Wildner Contributions by…

Book cover: Mastia Tarseion Revisited Mastia Tarseion Revisited

The Geographical Limits of Polybius Second Romano-Carthaginian Treaty

by Luis Silva Reneses

Book cover: Materiality of Air Materiality of Air

Edited by Tatiana Konrad

Book cover: Medical Theory and Practice in Early Modern Italy Medical Theory and Practice in Early Modern Italy

Volume 9

Edited by Sandra Cavallo Edited by John Henderson

Book cover: Nicolaus Copernicus in the Culture of Memory Nicolaus Copernicus in the Culture of Memory

Sedimentation of Knowledge

Contributions by Krzysztof Zamorski Contributions by Barbara Bienias Contributions by Radosław Sierocki Contributions by Florian-Jan…

Book cover: Nicole Oresme, Traitie de l’espere Nicole Oresme, Traitie de l’espere

A critical edition

Volume 35

edited by Ronald Thomson

Book cover: Non-Western Approaches in Environmental Humanities Non-Western Approaches in Environmental Humanities

Contributions by Héctor A. Peña Contributions by Anil Pradhan Contributions by Giacomo Bruni Contributions by…

Book cover: Orthodox Christianity and the Study of Nature Orthodox Christianity and the Study of Nature

Histories of Interaction

Volume 4

Edited by Kostas Tampakis Edited by Ronald L. Numbers

Book cover: Reframing Restoration Reframing Restoration

Rwanda Re-photographed 100 Years Later or the Reconstruction of Landscape Memory

By (author) Patrick Augenstein

Book cover: Science and Diplomacy Science and Diplomacy

The Max Planck Society in International Politics (1945–2000)

By (author) Carola Sachse

Book cover: Science and Sensibility Science and Sensibility

From the Heavens Above to the Earth Below

by David Howe

Book cover: The Archaeology of Irrigation Technology and Water Management in the Islamic World The Archaeology of Irrigation Technology and Water Management in the Islamic World

Proceedings of the Bahrain Conference, January 2024

Edited by Timothy Insoll Edited by Rachel Maclean Edited by Salman Almahari

Book cover: The History of the Physiologus in Early Medieval England The History of the Physiologus in Early Medieval England

Volume 5

By (author) Mercedes Salvador-Bello

Book cover: The People of Early Winchester The People of Early Winchester

Volume 9.1

Edited by Caroline M. Stuckert

Book cover: Waterscapes Archaeology Waterscapes Archaeology

Multi-Scalar Human-Environment Interactions in Coastal Lagoons

Edited by Alexandra Bivolaru Edited by Daniela Cottica Edited by Christophe Morhange

Book cover: Conrad Gessner, Fossilienbuch Conrad Gessner, Fossilienbuch

Ubersetzt und herausgegeben von Petra Schierl

by Conrad Gessner and edited by Petra Schierl and contributions by Urs B. Leu, Walter…

Book cover: Das Klima im Lichte der Geistes- und Sozialwissenschaften Das Klima im Lichte der Geistes- und Sozialwissenschaften

edited by Alexis Metzger, translated by Karin Becker

Book cover: Des savants et des dieux I Des savants et des dieux I

De la divination babylonienne au miracle grec, l'emergence de la science

by Pascal Richet

Book cover: Die “Schweizer Ärztinnen” der Habsburgermonarchie Die “Schweizer Ärztinnen” der Habsburgermonarchie

Weibliche Karrieren, Handlungsspielräume und Grenzüberschreitungen im späten 19. und frühen 20. Jahrhundert

By (author) Sabine Veits-Falk

Book cover: Die verborgene Tierwelt unserer Städte Die verborgene Tierwelt unserer Städte

Wie ich die Wildnis verließ und mich in der Stadt wiederfand

By (author) Marco Granata Translated by Peter Klöss Translated by A. Theodor Fasen

Book cover: Erinnerung an Wilhelm Gottlieb Hankel (1814–1899) aus Anlass seines 125. Todestages Erinnerung an Wilhelm Gottlieb Hankel (1814–1899) aus Anlass seines 125. Todestages

By (author) Bodo Geyer

Book cover: Ernst Haeckel: Ausgewählte Briefwechsel. Historisch-kritische Ausgabe. Bd. 22 Ernst Haeckel: Ausgewählte Briefwechsel. Historisch-kritische Ausgabe. Bd. 22

Korrespondenz zu Weltanschauung, Kunst und Literatur. Österreich und Schweiz August 1894 – August 1914

Edited by Jörn Bohr Edited by Thomas Bach Associate editor Daniela Prutscher

Book cover: Fluide Räume Fluide Räume

Schlaglichter auf Hispaniens Flusstäler

Edited by Jasmin Hettinger Edited by Janine Lehmann

Book cover: Forschen und Übersetzen Forschen und Übersetzen

Translation im (früh)modernen Wissenschaftssystem am Beispiel Frankreichs (1600–1815)

By (author) Garda Elsherif

Book cover: Kontroverse Sicherheit Kontroverse Sicherheit

Atomwirtschaft und Kernenergiediskussion in der Bundesrepublik Deutschland (1975–1992)

By (author) Sascha Brünig

Book cover: Nouvelles normes, surtout pas de panique! / Neue Normen, nur keine Panik! Nouvelles normes, surtout pas de panique! / Neue Normen, nur keine Panik!

Reguler les pollutions en Suisse a l'age industriel / Umweltverschmutzung und Regulierung in der industrialisierten Schweiz

edited by Nicolas Chachereau, Alexandre Elsig, Sabine Pitteloud and Tiphaine Robert

Book cover: Rohstoffmacht Russland Rohstoffmacht Russland

Eine globale Energiegeschichte

By (author) Jeronim Perović

Book cover: Socialitas, urbanitas, humanitas Socialitas, urbanitas, humanitas

Die Leipziger Sozietäten im 17. Jahrhundert zwischen Späthumanismus, lutherischer Orthodoxie und Frühaufklärung

By (author) Maximilian Görmar