New Emitters for OLEDs

The Coordination- and Photo-Chemistry of Mononuclear Neutral Copper(I) Complexes

By (author) Larissa Bergmann

Book cover: New Emitters for OLEDs

Extent: 277, 277 pages

Publisher: Logos Verlag Berlin

Subjects: Earth & Life Sciences 

Series: Beiträge zur organischen Synthese

Series volume number: 57

Language: English

Paperback (Published)

(January 2016)

ISBN: 9783832541835

5.71 x 8.27 inches

Price: $79.00

Out of stock

Organic light emitting diodes (OLEDs) enable the energy-efficient generation of light, and thus find application for displays or lighting. In particular, luminescent copper(I) complexes present a promising, resource- and cost-efficient class of emitting materials for OLEDs and have attracted enormous interest due to their high emission efficiencies and color tunability by ligand variation. The assessment of thermally activated delayed fluorescence (TADF) to copper(I) compounds has accelerated the development and investigation of several complex classes. Herein, novel emitting materials based on mononuclear neutral copper(I) complexes of the type [(N^N)Cu(P^P)] have been developed and a deeper understanding of the structureproperty relationships was achieved by comprehensive spectroscopical studies. The investigation of a large variety of complexes by absorption and emission spectroscopy, supported by theoretical calculations and electrochemical measurements, enabled a thorough understanding of the steric and electronic effects of the ligands on the complexes’ emission. Furthermore, the mechanism of thermally activated delayed fluorescence could be illustrated by means of time-resolved emission spectroscopy, and the intersystem crossing of a representative TADF complex determined in the solid state for the first time, which is essential for the design of efficient TADF materials.

  • By (author) Larissa Bergmann

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Book cover: Neue Strategien zur Modifikation von immobilisierten Building Blocks durch on-bead-Derivatisierung und funktionalisierende Abspaltung vom Trager Neue Strategien zur Modifikation von immobilisierten Building Blocks durch on-bead-Derivatisierung und funktionalisierende Abspaltung vom Trager

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Book cover: Synthesis of Functional Quinoxaline Derivatives for the Application in Biology and Materials Sciences Synthesis of Functional Quinoxaline Derivatives for the Application in Biology and Materials Sciences

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Book cover: Development of Rigid Aromatic Building Blocks for the Application in Material Sciences Development of Rigid Aromatic Building Blocks for the Application in Material Sciences

Volume 95

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Book cover: Heterobimetallic [2.2]Paracyclophane Complexes and Their Application in Photoredox Catalysis Heterobimetallic [2.2]Paracyclophane Complexes and Their Application in Photoredox Catalysis

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Book cover: Development of Novel Routes and Methods for the Semisynthesis of the Marine Steroid Demethylgorgosterol and Unnatural Analogs Development of Novel Routes and Methods for the Semisynthesis of the Marine Steroid Demethylgorgosterol and Unnatural Analogs

Volume 97

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Book cover: Synthesis and Application of [2.2]Paracyclophane Derivatives in Catalysis and Material Science Synthesis and Application of [2.2]Paracyclophane Derivatives in Catalysis and Material Science

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Book cover: Synthesis and design of unsymmetrical quinoxaline-based oligomer with tunable backbone Synthesis and design of unsymmetrical quinoxaline-based oligomer with tunable backbone

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Book cover: Synthesen trans-A2B2-substituierter Porphyrinlinker zur Darstellung photoaktiver oberflachenverankerter MOF-Dunnschichten Synthesen trans-A2B2-substituierter Porphyrinlinker zur Darstellung photoaktiver oberflachenverankerter MOF-Dunnschichten

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Volume 62

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Book cover: Metal-Catalyzed N-H and O-H Insertion from alpha-Diazocarbonyl Compounds Metal-Catalyzed N-H and O-H Insertion from alpha-Diazocarbonyl Compounds

Volume 79

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Book cover: Synthesis and Characterization of Luminescent Cu(I) Complexes Synthesis and Characterization of Luminescent Cu(I) Complexes

Volume 58

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