Synthese und Reaktivitatsstudien an Alan-substituierten Imidazolylen

By (author) Martin Simon

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Extent: 203 pages

Publisher: Logos Verlag Berlin

Subjects: Earth & Life Sciences 

Language: German

Paperback (Published)

(September 2019)

ISBN: 9783832549787

5.71 x 8.27 inches

Price: $67.00

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Seit das Konzept der Frustrierten Lewis Paare (FLPs) vorgestellt wurde, hat sich dieses Forschungsfeld zu einem der am intensivsten untersuchten Themengebiete der modernen Chemie entwickelt. Die modifizierbaren chemischen Eigenschaften von FLPs ermoglichen eine grosse Bandbreite von potentiellen Anwendungen. In den letzten Jahren wurde unter anderem eine Vielzahl FLP katalysierter Prozesse vorgestellt. Zusatzlich werden FLPs in der Grundlagenforschung zur Aktivierung bzw. Fixierung kleiner Molekule eingesetzt und werden als ambiphile Liganden untersucht. Im Rahmen dieser Arbeit wurde die Synthese von neuartigen FLPs auf Basis von Alan-substituierten Imidazolylen untersucht. Dabei konnten mittels unterschiedlicher Zugange interessante Einblicke in mogliche Bildungspfade von verschiedenen Strukturmotiven erhalten werden. Erganzend wurden Reaktivitatsstudien mit kleinen Molekulen und mit Ubergangsmetallhalogenid-Komplexen durchgefuhrt.

  • By (author) Martin Simon

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