Radical Brook Rearrangement

A unique book that incorporates of research on radical Brook rearrangements.

Chapter 1 Introduction
Chapter 2 Generation of a-siloxy radicals with a-silyl alcohol through radical Brook rearrangement
2.1 Metal free reactions
2.2 Metal-catalyzed reactions
2.3 Photocatalyzed reactions
2.4 Electrophotocatalyzed reactions
2.4 Other reactions
 
Chapter 3 Generation of a-siloxy radicals with acylsilane through radical Brook rearrangement
3.1 Radical initiation
3.2 Metal-catalyzed reactions
3.3 Photocatalyzed reactions
3.4 Other reactions
 
Chapter 4 Generation of a-siloxy silyl radicals with (TMS)3SiOH through radical Brook rearrangement
4.1 Metallaphotoredox reactions
4.2 Photoredox reactions
4.3 Metallaphotoredox reaction with (TMS)3SiNHAd
 
Chapter 5 Generation of siloxycarbenes for nucleophilic addition reaction
5.1 Aldehydes or ketones as electrophiles
5.2 Other electrophilic reagents
 
Chapter 6 Generation of siloxycarbenes for insertion reaction
6.1 Carbene insertion reactions into O?H bonds
6.2 Carbene insertion reactions into N?H bonds
6.3 Carbene insertion reactions into other X?H bonds
6.4 Carbene insertion reactions into B?C bonds
6.5 Carbene insertion reactions into C?H bonds
 
Chapter 7 Generation of siloxycarbenes for cycloaddition reaction
7.1 [2+1] cycloaddition with alkynes
7.2 [2+1] cycloaddition with alkenes
7.3 [4+1] cycloaddition with dienes and a,ß-unsaturated ketones
7.4 [2+2] Cycloaddition Reaction of a-Ketoacylsilanes with Imines
7.5 other cyclization reaction
 
Chapter 8 Generation of siloxycarbenes for metal siloxycarbene reaction
8.1 Metal siloxycarbene reactions
8.2 Aminooxycarbene Reactions
Chapter 9 Generation of silenes through radical Brook rearrangement
9.1 Insertion reactions
9.2 [2+2] Cycloaddition reactions
9.3 [4+2] Cycloaddition reactions
9.4 Other reactions
 
Chapter 10 Reference
 

• By (author) Xiao Shen
• By (author) Yunxiao Zhang
• By (author) Gang Zhou