Mixed-Valence Systems

Covers new developments in the field of mixed-valence electron transfer, including design, synthesis and applications of mixed-valence compounds with various inorganic and organic redox-active centers.

1. Introduction and Fundamentals of Mixed-Valence Chemistry
2 The Conceptual Understanding of Mixed-Valence Compounds and Its Extension to General Stereoisomerism
3 Quantum-Chemical Approaches to Treat Mixed-Valence Systems Realistically for Delocalized and Localized Situations
4 Mixed Valency in Ligand Bridged Diruthenium Complexes
5 Electronic Communication in Mixed-Valence (MV) Ethynyl, Butadiyndiyl and Polyynediyl Complexes of Iron, Ruthenium and Other Late Transition Metals
6 Electron Transfer in Mixed-Valence Ferrocenyl-Functionalized 5- and 6-Membered Heterocycles
7 Electronic Coupling and Electron Transfer in Mixed-Valence Systems with Covalently-Bonded Dimetal Units
8 Mixed-Valence Electron Transfer of Cyanide-Bridged Multimetallic Systems
9 Organic Mixed-Valence Systems: Towards Fundamental Understanding of Charge/Spin Transfer Materials
10 Mixed-Valence Complexes in Biological and Bio-Mimic Systems
11 Control of Electron Coupling and Electron Transfer through Non-Covalent Interactions in Mixed-Valence Systems
12 Stimulus-Responsive Mixed-Valence and Related Donor-Acceptor Systems
13 Mixed Valency in Extended Materials
14 Near-Infrared Electrochromism Based on Intervalence Charge Transfer
15 Manipulate Metal-to-Metal Charge Transfer towards Switchable Functions

• Edited by Yu-Wu Zhong
• Edited by Chun Y. Liu
• Edited by Jeffrey R. Reimers